Current research projects

Image Performance tests of refrigerant compressors
Image Swirl-free on the move...
Image Development of test methods and test rigs for stationary integrated refrigeration units
Image Service offer for Leak Detection and Tightness Test
Image Innovative cryogenic cooling system for the recondensation / liquefaction of technical gases up to 77 K
Image Characterisation of Superconductors in Hydrogen Atmosphere
Image Measurement of insulated packaging
Image Low noise and non metallic liquid-helium cryostat
Image Ionocaloric cooling
Image 3D - Air flow sensor
Image Optimizing HVAC operation with machine learning
Image Thermal engines
Image Mass Spectrometer
Image Hybrid- Fluid for CO2-Sublimation Cycle
Image Helium extraction from natural gas
Image Investigation of materials

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Hybrid- Fluid for CO2-Sublimation Cycle

Dr. Joachim Germanus

+49-351-4081-5412

Cryogenic cooling by CO2 sublimation

The objective of the research project is the selection and qualification of a new refrigeration fluid. The so called “Hybrid-Fluid” should be used both as a lubricant for compressor lubrication and as a heat transfer fluid in a CO2 sublimator. Such a fluid is a requirement for the implementation of a closed low GWP CO2 sublimation refrigeration cycle. It could be used as a replacement for previous high-GWP cold steam refrigeration cycles in a temperature range down to -80 °C.

The project idea is based on the intension to find a fluid that combines the advantages of compressor lubrication and heat transfer in a sublimator. It has to be clarified which fluid fulfill these requirements best. It would be advantageous to use a fluid which has a good solubility for CO2 at low temperatures in order to achieve a lower viscosity for a better flow characteristic in the sublimator. In addition, the viscosity should allow sufficient lubrication of the compressor under CO2 compression. On the other hand, a fluid with low solubility of CO2 would not contribute to the improved viscosity reduction in the sublimator but would show advantages for lubrication of the compressor instead.

Areas of application for cooling temperatures below -50 °C are numerous. Examples include applications in the fields of environmental simulation, medical and pharmaceutical technology, cryopreservation, freeze-drying and food technology. Upon successful completion of the research project, an important prerequisite for operating closed sublimation refrigeration cycles will be created to replace R-23 with the environmentally friendly refrigerant CO2 in a range of different applications.

In the refrigeration market in the EU currently a shortage of fluorinated refrigerants with high global warming potential (GWP) values is observed. This goes along with rising prices which have already reached several hundred Euros per kilogram for the low temperature refrigerant R-23. No relief is expected since with the commencement of the EU F-Gas Regulation in 2015 emission reduction provisions have been made which are binding for the next decades. Thus, pressure on affected manufacturers is growing to look for replacement refrigerants for their applications. However, for cooling temperatures below -50 °C, there are currently no non-flammable refrigerant alternatives. The CO2 sublimation is a suitable way to realize cooling temperatures below -50 °C with a non-flammable refrigerant.


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Further Projects - Research and Development

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Characterisation of Superconductors in Hydrogen Atmosphere

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Development of a Cryogenic Magnetic Air Separation Unit

Oxygen Enrichment by Applied Cryogenic Magnetohydrodynamics

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